Metal centres of nitrogenase
Kim and Rees proposed structural models, from a 2.7 Å crystal structure, for the metal centres of the nitrogenase molybdenum-iron protein: the FeMo-cofactor, built from iron-sulfur and molybdenum-iron-sulfur clusters, and the P-clusters, made of two 4Fe:4S clusters.
As reported in: Kim, Rees (1992). Structural Models for the Metal Centers in the Nitrogenase Molybdenum-Iron Protein. Science. doi:10.1126/science.1529354
Abstract only